Chromium-Molybdenum 4140 Steel

AISI 4140 is a medium-carbon chromium-molybdenum (Cr-Mo) alloy steel known for its high strength, excellent toughness, good hardenability, and reliable fatigue resistance. It bridges the gap between plain carbon steels and higher-alloy grades such as 4340, offering a cost-effective high-performance solution.

4140 responds exceptionally well to quenching and tempering, making it one of the most widely used alloy steels in automotive, oil & gas, forging, heavy machinery, and power transmission industries.

Chemical Composition

Element%Metallurgical Function
Carbon (C)0.38 – 0.43Strength & hardness
Chromium (Cr)0.80 – 1.10Hardenability, wear resistance
Molybdenum (Mo)0.15 – 0.25Toughness, high-temperature strength
Manganese (Mn)0.75 – 1.00Strength, impact resistance
Silicon (Si)0.15 – 0.35Deoxidation, strength
Phosphorus (P)≤ 0.035Controlled impurity
Sulfur (S)≤ 0.040Machinability
Iron (Fe)BalanceBase metal

Microstructure & Metallurgy

• Annealed: Ferrite + pearlite
• Normalized: Fine pearlitic structure
• Quenched: Martensitic structure
• Tempered: Tempered martensite for strength–toughness balance
• Cr and Mo delay pearlite formation enabling deep martensitic hardening

Mechanical Properties

ConditionTensile StrengthYield StrengthElongationHardness
Annealed655 – 760 MPa415 – 520 MPa22 – 25%200 – 217 HB
Normalized850 – 950 MPa650 – 720 MPa18 – 22%~240 HB
Quenched & Tempered900 – 1,080 MPa750 – 850 MPa12 – 18%28 – 45 HRC
Surface HardenedUp to 60 HRC

Key Characteristics

Excellent Hardenability
• Uniform hardness through medium-thick sections
• Superior to plain carbon steels such as C45 / 1045

High Strength & Fatigue Resistance
• Ideal for rotating and cyclically loaded components
• Long service life under mechanical stress

Good Wear & Abrasion Resistance
• Responds well to nitriding, carburizing, and induction hardening

Good Impact Toughness
• Resists shock loading without brittle failure

Elevated Temperature Performance
• Retains integrity up to ~400–450°C

Heat Treatment & Processing

Annealing: 830–860°C, furnace cooled
Normalizing: 870–900°C, air cooled
Quenching: Oil or polymer quench
Tempering: 200–650°C depending on application
Surface Hardening: Nitriding, induction, limited carburizing

Fabrication & Machining

• Good machinability in annealed/normalized condition
• Weldability is fair; preheating (200–300°C) required
• Hot forming preferred

Available Forms

✔ Hot rolled & forged round bars
✔ Bright bars (cold finished)
✔ Flat, square & hex bars
✔ Plates & cut blocks
✔ Hollow bars & seamless tubes
✔ Pre-hardened / Q&T components

Standards & Equivalents

StandardEquivalent
AISI / SAE4140
ASTMA29, A322
DIN42CrMo4
EN1.7225
JISSCM440
BSEN19

Applications

Automotive: Crankshafts, axles, gears, steering components
Oil & Gas: Drill collars, studs, wellhead parts
Industrial: Hydraulic rods, spindles, press rams
Forging: Die holders, tool bases, forged parts

4140 vs 4340

Property41404340
Alloy SystemCr-MoNi-Cr-Mo
HardenabilityHighVery High
ToughnessGoodExcellent
CostLowerHigher
Typical Section SizeMediumVery thick

Advantages

✔ Excellent strength-to-cost ratio
✔ Deep and uniform hardening capability
✔ Good machinability before heat treatment
✔ Long service life
✔ Widely available global standard

Limitations

⚠ Lower toughness than 4340 in extreme shock
⚠ Controlled welding required
⚠ Limited corrosion resistance